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So far jamie has created 205 blog entries.

Mia Borden, PhD

Mia Borden, PhD. On June 22, Mia gave an outstanding final public oral to the department on her work in the Doyle Lab, which focused on asymmetric Ni-catalyzed cross-couplings! She recently headed south to UNC Chapel Hill, where she will be a postdoctoral associate in the lab of Prof. Frank Leibfarth. Congratulations on

Mia Borden, PhD2020-09-11T21:22:13-07:00

Jesús Estrada: Chem Ph.D, Merck Scientist, “Dreamer”

Jesús Estrada: Chem PhD, Merck Scientist, “Dreamer”. In a recent Princeton Chemistry Alumni Spotlight, Doyle Lab graduate Jesús Estrada, Ph.D. ‘19, reflected on the importance of the DACA program in allowing him to achieve his educational goals and become a Senior Scientist at Merck. Check out the article here!

Jesús Estrada: Chem Ph.D, Merck Scientist, “Dreamer”2020-09-11T21:23:40-07:00

Nucleophilic (Radio)Fluorination of Redox-Active Esters via Radical-Polar Crossover Enabled by Photoredox Catalysis

Nucleophilic (Radio)Fluorination of Redox-Active Esters via Radical-Polar Crossover Enabled by Photoredox Catalysis. Eric and John’s work in collaboration with BMS on a redox-neutral method for nucleophilic fluorination of phthalimide esters was just published in JACS (check it out here)! Congrats on completing an exciting project!

Nucleophilic (Radio)Fluorination of Redox-Active Esters via Radical-Polar Crossover Enabled by Photoredox Catalysis2020-09-11T21:24:44-07:00

Regioselective Cross-Electrophile Coupling of Epoxides and (Hetero)aryl Iodides via Ni/Ti/Photoredox Catalysis

Regioselective Cross-Electrophile Coupling of Epoxides and (Hetero)aryl Iodides via Ni/Ti/Photoredox Catalysis. Marvin’s work on developing a novel methodology for cross-coupling epoxides and aryl iodides using Ni/Ti/Photoredox catalysis was just published in ACS Catalysis! The mild cross-electrophile approach tolerates three distinct classes of epoxides and a broad scope of aryl iodides. Check it out here!

Regioselective Cross-Electrophile Coupling of Epoxides and (Hetero)aryl Iodides via Ni/Ti/Photoredox Catalysis2020-09-11T21:25:26-07:00

Eric Webb, PhD

Eric Webb, PhD. On April 29th, Eric Webb gave his departmental Final Public Oral to a packed Zoom audience, making the Doyle Lab’s first virtual thesis defense a success! Congrats on your PhD, Dr. Webb!

Eric Webb, PhD2020-09-11T21:25:47-07:00

Role of Electron-Deficient Olefin Ligands in a Ni-Catalyzed Aziridine Cross-Coupling To Generate Quaternary Carbons

Role of Electron-Deficient Olefin Ligands in a Ni-Catalyzed Aziridine Cross-Coupling To Generate Quaternary Carbons. Jesús, Wendy, and Stephen’s work on elucidating the mechanism of Ni-catalyzed Negishi Couplings of Aziridines, and the associated ligand effects of electron deficient olefin ligand, Fro-DO, was just published in JACS! Congrats on the completion of an exciting project!

Role of Electron-Deficient Olefin Ligands in a Ni-Catalyzed Aziridine Cross-Coupling To Generate Quaternary Carbons2020-09-11T21:26:32-07:00

Izzy’s Generals

Izzy’s Generals. Congratualtions to Izzy on recently passing her “zoom”erals exam! Fantastic job, and we’ll have to celebrate with a champagne toast when we all return to lab!

Izzy’s Generals2020-09-11T21:27:03-07:00

Congratulations Talia!

Congratulations Talia!. Talia recently packed up her car (with some help from her dog Bialy) and headed north to the Boston area to begin a new position at Snapdragon Chemistry. You certainly will be missed by all in the Doyle Lab, but we congratulate you on landing a fantastic job and wish you

Congratulations Talia!2020-09-11T21:27:39-07:00

Nickel/Photoredox-Catalyzed Methylation of (Hetero)aryl Chlorides Using Trimethyl Orthoformate as a Methyl Radical Source

Nickel/Photoredox-Catalyzed Methylation of (Hetero)aryl Chlorides Using Trimethyl Orthoformate as a Methyl Radical Source. Stavros, Ben, and Makeda’s work, in collaboration with Mike Zacuto at Celgene, to “photo-eliminate a gap in the methylation methodology” has recently been published in JACS! Congrats to the team and great work!

Nickel/Photoredox-Catalyzed Methylation of (Hetero)aryl Chlorides Using Trimethyl Orthoformate as a Methyl Radical Source2020-09-11T21:28:24-07:00

Synthesis of β-Phenethylamines via Ni/Photoredox Cross-Electrophile Coupling of Aliphatic Aziridines and Aryl Iodides

Synthesis of β-Phenethylamines via Ni/Photoredox Cross-Electrophile Coupling of Aliphatic Aziridines and Aryl Iodides. Talia, Junyi, and Mani’s work on developing a new Ni/Photoredox methodology to synthesize pharmaceutically relevant β-Phenethylamines was recently accepted and published in JACS! Great work!

Synthesis of β-Phenethylamines via Ni/Photoredox Cross-Electrophile Coupling of Aliphatic Aziridines and Aryl Iodides2020-09-11T21:28:56-07:00
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