Regioselective Cross-Electrophile Coupling of Epoxides and (Hetero)aryl Iodides via Ni/Ti/Photoredox Catalysis

Marvin’s work on developing a novel methodology for cross-coupling epoxides and aryl iodides using Ni/Ti/Photoredox catalysis was just published in ACS Catalysis! The mild cross-electrophile approach tolerates three distinct classes of epoxides and a broad scope of aryl iodides. Check it out here!

Regioselective Cross-Electrophile Coupling of Epoxides and (Hetero)aryl Iodides via Ni/Ti/Photoredox Catalysis2022-12-30T22:51:44-08:00

Role of Electron-Deficient Olefin Ligands in a Ni-Catalyzed Aziridine Cross-Coupling To Generate Quaternary Carbons

Jesús, Wendy, and Stephen’s work on elucidating the mechanism of Ni-catalyzed Negishi Couplings of Aziridines, and the associated ligand effects of electron deficient olefin ligand, Fro-DO, was just published in JACS! Congrats on the completion of an exciting project!

Role of Electron-Deficient Olefin Ligands in a Ni-Catalyzed Aziridine Cross-Coupling To Generate Quaternary Carbons2022-12-30T22:53:08-08:00

Triplet d-d Excited States of Ni(II) Complexes Relevant to Photoredox Catalysis

Congrats to Stephen on recently publishing a study on how Ni(II) intermediates proposed in photocatalytic cycles can interact with light and lead to Ni-C bond homolysis. This spectroscopic and organometallic mechanistic work in collaboration with the Scholes and Castellano labs is now available to read in JACS! Congrats all!

Triplet d-d Excited States of Ni(II) Complexes Relevant to Photoredox Catalysis2022-12-30T22:56:26-08:00
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